Triaquadichlorido[5-(4-pyridinio)tetrazolato-κN 2]cobalt(II) monohydrate
نویسنده
چکیده
The title compound, [CoCl(2)(C(6)H(5)N(5))(H(2)O)(3)]·H(2)O, was synthesized by hydro-thermal reaction of CoCl(2) with 4-(2H-tetra-zol-5-yl)pyridine. The Co(II) cation is coordinated by two Cl(-) ions, one N atom from the 5-(4-pyridinio)tetra-zolate zwitterion and three O atoms from three water mol-ecules in a distorted octa-hedral geometry. In the crystal, mol-ecules are linked into a three-dimensional network by N-H⋯Cl hydrogen bonds and O-H⋯O/N/Cl hydrogen bonds involv-ing both coordinated and uncoordinated water mol-ecules. Strong π-π stacking is present between parallel pyridinium and tetra-zolate rings [centroid-centroid distances = 3.411 (2) and 3.436 (2) Å].
منابع مشابه
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009